A NOVEL VIC-DIOXIME WITH CROWN ETHER MOIETIES

被引：54
作者：
GOK, Y
KANTEKIN, H
机构：
[1] Department of Chemistry, Karadeniz Technical University, Trabzon
来源：
CHEMISCHE BERICHTE | 1990年 / 123卷 / 07期
关键词：
Cobalt complexes; Crown ethers; Imidazolines; Oxime complexes;
D O I：
10.1002/cber.19901230706
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The novel vic‐dioxime 2 has been synthesized by reaction of the thiourea 1 with cyanogen N,N′‐dioxide. The IR and NMR data indicate that 2 is the (E,Z) isomer. However, in the Co(III) complex of 2, the metal ion is coordinated to the nitrogen atoms of the vic‐dioxime moiety as in the case of the (E, E) isomers. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
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页码：1479 / 1480
页数：2
相关论文
共 17 条
[1]   COMPREHENSIVE COORDINATION CHEMISTRY OF ALKALI AND ALKALINE-EARTH CATIONS WITH MACROCYCLIC MULTIDENTATES - LATEST POSITION [J].
BAJAJ, AV ;
POONIA, NS .
COORDINATION CHEMISTRY REVIEWS, 1988, 87 :55-213
[2]  
DANIEL A, 1967, TETRAHEDRON LETT, V13, P1145
[3]  
ERBAS M, 1987, J ORGANOMET CHEM, V319, P197
[4]   C-13 NMR OF PARA-SUBSTITUTED HYDRAZONES, PHENYLHYDRAZONES, OXIMES, AND OXIME METHYL ETHERS - SUBSTITUENT EFFECTS ON THE IMINYL CARBON [J].
GORDON, MS ;
SOJKA, SA ;
KRAUSE, JG .
JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (01) :97-100
[5]  
GRUNDMANN C, 1965, LIEBIGS ANN CHEM, V687, P191
[6]  
GUL A, 1983, TETRAHEDRON LETT, P2537
[7]   GEOMETRICAL DEPENDENCES OF CARBON-NITROGEN COUPLING-CONSTANTS - OXIMES [J].
LICHTER, RL ;
DORMAN, DE ;
WASYLISHEN, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (03) :930-932
[8]   NOVEL TRANSITION-METAL COMPLEXES OF CAMPHORQUINONE DIOXIME LIGANDS [J].
MA, MS ;
ANGELICI, RJ .
INORGANIC CHEMISTRY, 1980, 19 (02) :363-370
[9]   REDOX-SWITCHED CROWN ETHERS MONOCROWN-BISCROWN INTERCONVERSION COUPLED WITH REDOX OF A THIOL-DISULFIDE COUPLE [J].
MINAMI, T ;
SHINKAI, S ;
MANABE, O .
TETRAHEDRON LETTERS, 1982, 23 (49) :5167-5170
[10]  
NAKAMURA A, 1978, J CHEM SOC DA, P488
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