IRIDIUM OXIDE-FILMS VIA SOL-GEL PROCESSING

被引：54

作者：

OSAKA, A ^{[1
]}

TAKATSUNA, T ^{[1
]}

MIURA, Y ^{[1
]}

机构：

[1] OKAYAMA UNIV,FAC ENGN,DEPT APPL CHEM,OKAYAMA 700,JAPAN

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1994年 / 178卷

关键词：

D O I：

10.1016/0022-3093(94)90300-X

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Iridium (III) ethoxide and hydrogen hexachloroiridate (IV) films were formed on glass substrates by drop-and-spread and dip-coating procedures, and heat treated to IrO2 films. Effect of additives such as ethylene glycol, H2O, and HNO3 oil the microstructure of the heated films was studied as well as that of drying and heating schedules. Preciptation of metallic Ir found for several films was correlated to the high electronegativity of Ir.

引用

页码：313 / 319

页数：7

共 9 条

[1]

Brinker C. J., 1990, SOL GEL SCI, P45

[2]

Huheey J.E., 1993, INORG CHEM, P187

[3] ANODIC EVOLUTION OF OXYGEN ON IRIDIUM OXIDE ELECTRODE [J].

IWAKURA, C ;

TADA, H ;

TAMURA, H .

DENKI KAGAKU, 1977, 45 (04) :202-207

[4]

KOBAYASHI H, 1990, SURF TECHNOL, V41, P325

[5] SOL-GEL CHEMISTRY OF TRANSITION-METAL OXIDES [J].

LIVAGE, J ;

HENRY, M ;

SANCHEZ, C .

PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (04) :259-341

[6] FORMATION OF IRIDIUM METAL IN THERMALLY PREPARED IRIDIUM DIOXIDE COATINGS [J].

LODI, G ;

DEBATTISTI, A ;

BENEDETTI, A ;

FAGHERAZZI, G ;

KRISTOF, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 256 (02) :441-445

[7]

MATHEISS LF, 1976, PHYS REV B, V13, P2433

[8] OXIDATION-STATE CHANGES AND STRUCTURE OF ELECTROCHROMIC IRIDIUM OXIDE-FILMS [J].

MCINTYRE, JDE ;

PECK, WF ;

NAKAHARA, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (06) :1264-1268

[9] ANODICALLY ELECTRODEPOSITED IRIDIUM OXIDE-FILMS (AEIROF) FROM ALKALINE-SOLUTIONS FOR ELECTROCHROMIC DISPLAY DEVICES [J].

YAMANAKA, K .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1989, 28 (04) :632-637

← 1 →