A NOVEL CATALYST SYSTEM FOR ETHANOL GASIFICATION

被引：34

作者：

LUENGO, CA ^{[1
]}

CIAMPI, G ^{[1
]}

CENCIG, MO ^{[1
]}

STECKELBERG, C ^{[1
]}

LABORDE, MA ^{[1
]}

机构：

[1] UNIV BUENOS AIRES,DEPT CHEM ENGN,BUENOS AIRES,ARGENTINA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1992年 / 17卷 / 09期

关键词：

D O I：

10.1016/0360-3199(92)90086-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel/copper/chromium catalysts supported on porous alumina were synthesized. Samples of 4.0% Ni/0.75% Cu/0.25% Cr on alpha-Al2O3 were run in a fixed-bed reactor system dedicated to the steam reforming of ethanol. The operating temperatures ranged from 573 to 823 K, the water/ethanol mole ratios from 0.4 to 2.0 and the space velocities from 2.5 to 15 h-1. The data reveal high activity of this catalyst for ethanol gasification, as well as good selectivity in H-2 and CO. Comparison of these results with thermodynamic equilibrium values indicate that the catalytic effect is more pronounced at lower temperatures.

引用

页码：677 / 681

页数：5

共 10 条

[1]

BOND GC, 1962, CATALYSIS METALS, pCH15

[2]

COWLEY SJ, 1983, UNPUB

[3]

FINEGOLD G, 1980, 4TH P INT S ALC FUEL, P96

[4] HYDROGEN-PRODUCTION BY THE STEAM REFORMING OF ETHANOL - THERMODYNAMIC ANALYSIS [J].

GARCIA, EY ;

LABORDE, MA .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1991, 16 (05) :307-312

[5]

KODAMA K, 1984, Patent No. 59189935

[6] CATALYSIS OF CARBON-MONOXIDE AND CARBON-DIOXIDE METHANATION BY CEAL2, CECO2, CENI2, CO, AND NI [J].

LUENGO, CA ;

CABRERA, AL ;

MACKAY, HB ;

MAPLE, MB .

JOURNAL OF CATALYSIS, 1977, 47 (01) :1-10

[7]

LUENGO CA, 1980, 4TH P INT S ALC FUEL, P120

[8]

TAKEUSHI, 1978, Patent No. 88155634

[9]

VOECKS GE, 1980, 4TH P INT S ALC FUEL, P93

[10]

YAMAGUCHI I, 1980, 80TH P ANN M SOC AUT

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