CHEMISTRY OF PYRROLIC COMPOUNDS .8. DIPYRRYLTHIONES

被引：51
作者：
CLEZY, PS
SMYTHE, GA
机构：
[1] Department of Organic Chemistry, University of New South Wales, Kensington, NSW, 2033
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 01期
关键词：
D O I：
10.1071/CH9690239
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of symmetrical dipyrrylthiones have been prepared by the action of thiophosgene on the appropriate 5-unsubstituted pyrrole. From an examination of their spectroscopic properties it is concluded that these compounds exist predominantly as the thione tautomer. Some chemical properties of the system are described including the conversion of the thiones into ketones by treatment with alkaline peroxide. The mass spectra of dipyrrylthiones and dipyrrylketones are compared. © 1969, CSIRO. All rights reserved.
引用
收藏
页码：239 / &
相关论文
共 22 条
[1]  
ANDRIEU C, 1965, B SOC CHIM FR, P2457
[2]  
BALLANTINE JA, 1966, TETRAHEDRON S7, P241
[3]  
Bellamy L., 2013, INFRA RED SPECTRA CO
[4]   The light absorption of organic compounds, and the nature of unsaturated linkages [J].
Burawoy, A .
JOURNAL OF THE CHEMICAL SOCIETY, 1939, :1177-1188
[5]   THIONES AND THIALS [J].
CAMPAIGNE, E .
CHEMICAL REVIEWS, 1946, 39 (01) :1-77
[6]   DETERMINING MOLECULAR STRUCTURE BY NUCLEAR MAGNETIC RESONANCE OF HYDROGEN [J].
CHAMBERLAIN, NF .
ANALYTICAL CHEMISTRY, 1959, 31 (01) :56-77
[7]   CHEMISTRY OF PYRROLIC COMPOUNDS .2. SOME ASPECTS OF CHEMISTRY OF DIPYRRYL KETONES [J].
CLEZY, PS ;
NICHOL, AW .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1965, 18 (12) :1977-&
[8]   CHEMISTRY OF PYRROLIC COMPOUNDS .1. SYNTHESIS OF OXYPORPHYRINS [J].
CLEZY, PS ;
NICHOL, AW .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1965, 18 (11) :1835-&
[9]  
CLOW A, 1940, T FARADAY SOC, V36, P685
[10]  
Fischer H, 1931, LIEBIGS ANN CHEM, V489, P62
123