SYNERGISTIC EXTRACTION STUDIES OF AM(III) AND EU(III) FROM PERCHLORIC-ACID WITH 4-BENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-THIONE (BMPPT) AND TRI-NORMAL-OCTYLPHOSPHINE OXIDE (TOPO) IN BENZENE

被引：19

作者：

SMITH, BF

JARVINEN, GD

MILLER, GG

RYAN, RR

PETERSON, EJ

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM,, USA, Los Alamos Natl Lab, Los Alamos, NM, USA

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1987年 / 5卷 / 05期

关键词：

EUROPIUM; -; Extraction; EXTRACTION;

D O I：

10.1080/07366298708918599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The extraction of Am(III) and Eu(III) from aqueous HClO//4 by BMPPT and TOPO in benzene was studied. The ligand BMPPT gave no detectable extraction in the ranges studied, but when BMPPT and TOPO were combined, a synergistic extraction was observed with a selectivity for Am(III) over Eu(III) (K//d//A//m equals 7. 5, Am/Eu equals 68, pH 3. 0, 0. 01 M left bracket TOPO right bracket , 0. 30 M left bracket BMPPT right bracket ).

引用

页码：895 / 908

页数：14

共 3 条

[1] Extraction of Eu(III) and Am(III) by 1-phenyl-3-methyl-4-acetylpyrazol-5-one (HPMAP) and tri-n-octylphosphine oxide (TOPO) in a room-temperature ionic liquid
Gujar, Rajesh B.
Sengupta, Arijit
Murali, Mallekav S.
Mohapatra, Prasanta K.
SEPARATION SCIENCE AND TECHNOLOGY, 2017, 52 (14) : 2318 - 2327
[2] Extraction of Rare Earth Elements(III) with Mixtures of Some New Tridentate Carbamoylmethylphosphine Oxides and 4-Benzoyl-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one from Hydrochloric Acid Solutions
A. N. Turanov
V. K. Karandashev
V. A. Khvostikov
O. I. Artyushin
N. A. Bondarenko
Russian Journal of General Chemistry, 2021, 91 : 383 - 388
[3] Extraction of Rare Earth Elements(III) with Mixtures of Some New Tridentate Carbamoylmethylphosphine Oxides and 4-Benzoyl-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one from Hydrochloric Acid Solutions
Turanov, A. N.
Karandashev, V. K.
Khvostikov, V. A.
Artyushin, O., I
Bondarenko, N. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (03) : 383 - 388

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