NOVEL ONE-POT SYNTHESIS OF 1-IODO-1-TRIMETHYLSILYL 1,3-DIENES

被引：6

作者：

SHEN, YC

WANG, TL

XIA, W

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 03期

关键词：

D O I：

10.1039/p19930000389

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodine was added to 3-(trimethylsilyl)allylic phosphonium ylide regiospecifically to give 3-iodo-3-trimethylsilyl allylic phosphonium ylide, which reacted with carbonyl compounds to give 1-iodo-1-trimethylsilyl 1,3-dienes with high stereoselectivity in good yield.

引用

页码：389 / 391

页数：3

共 21 条

[1]

BESTMANN H, 1964, LIEBIGS ANN CHEM, V674, P11

[2]

BESTMANN HJ, 1989, TETRAHEDRON LETT, V30, P2911

[3] SYNTHETIC STUDIES ON DAMASCENONES [J].