UNEXPECTED 2-ELECTRON TRANSFER IN CYCLIC HYDRAZINES - A VOLTAMMETRIC ANALYSIS

被引：31
作者：
DIETRICH, M
HEINZE, J
FISCHER, H
NEUGEBAUER, FA
机构：
[1] UNIV FREIBURG,INST PHYS CHEM,ALBERTSTR 21,D-7800 FREIBURG,FED REP GER
[2] MAX PLANCK INST MED RES,ORGAN CHEM ABT,D-6900 HEIDELBERG 1,FED REP GER
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1986年 / 25卷 / 11期
关键词：
ORGANIC COMPOUNDS - Electronic Properties;
D O I：
10.1002/anie.198610211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Conformational changes could be shown to give rise to unusual cyclovoltammograms in the case of cyclic hydrozines. At low temperatures, these compounds formally show a two-electron transfer; in the case of the phenyl derivative the rare crossing effect is observed. All other methods of conformation analysis failed in this case.
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收藏
页码：1021 / 1023
页数：3
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