INTRAMOLECULAR MULTIPLE-SCATTERING IN ELECTRON-DIFFRACTION FROM FLUORO-METHYL HALIDES

被引：8

作者：

MEIER, C ^{[1
]}

VOLKMER, M ^{[1
]}

LIESCHKE, J ^{[1
]}

FINK, M ^{[1
]}

BOWERING, N ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT PHYS,AUSTIN,TX 78712

来源：

ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1994年 / 30卷 / 2-3期

关键词：

D O I：

10.1007/BF01426070

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Relative elastic differential cross sections for scattering of 1 keV electrons from CF3H, CF4, CF3Cl, CH3F and CH3Cl molecules were measured for momentum transfer from 3 angstrom-1 to 29 angstrom-1. The oscillatory residuals remaining after substraction of the atomic scattering and the molecular interference contributions calculated in the independent atom model are ascribed to the influence of intramolecular multiple scattering. The data reflect the dominant contributions of the CF3-group and show larger oscillations than obtained from triple scattering calculations according to the method of Liu and Bonham using the second Born approximation.

引用

页码：183 / 187

页数：5

共 31 条

[1]

Bartell L.S., 1988, STATUS ELECT SCATTER, P55

[2] STRUCTURES OF CF3CL AND CH3CL [J].