COLLISION-INDUCED DECOMPOSITION OF EXCITED PARA-DICHLOROBENZENE

被引：14

作者：

SHIMODA, A

KOHSO, Y

HIKIDA, T

ICHIMURA, T

MORI, Y

机构：

[1] Department of Chemistry, Tokyo Institute of Technology, Meguro Tokyo, Ohokayama

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)80528-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photodecomposition of p-dichlorobenzene of 253.7 nm has been measured in the presence of ethane. The quantum yield of monochlorobenzene formation is found to be 0.95 at ethane pressures higher than 200 Torr. The addition of CO2 or SF6 to the mixture of p-dichlorobenzene and 50 or 100 Torr ethane causes an increase in the quantum yield of photodecomposition, indicating collision-induced decomposition of excited p-dichlorobenzene. © 1979.

引用

页码：348 / 349

页数：2

共 6 条

[1]

GUTTMAN C, 1971, J CHEM PHYS, V55, P5561

[2] FLUORESCENCE OF MONOCHLOROBENZENE IN VAPOR-PHASE [J].