TOTAL SYNTHESIS OF (+-)-PATCHOULI ALCOHOL AND (+-)-SEYCHELLENE VIA A COMMON HOMOISOTWISTANE INTERMEDIATE

被引：43

作者：

YAMADA, K

KYOTANI, Y

MANABE, S

SUZUKI, M

机构：

[1] Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, Nagoya

来源：

TETRAHEDRON | 1979年 / 35卷 / 03期

关键词：

D O I：

10.1016/0040-4020(79)80064-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Base-catalyzed cyclization of a conjugated cyclohexenone derivative 16 afforded in a single step a homoisotwistane derivative 17, which was converted to a ketone 22. Both (±)-patchouli alcohol 1 and (±)-seychellene 2 were synthesized using reactions at the bridgehead position (C-7) of a bicyclo[3.3.1]nonan-2-one system contained in 22. © 1979.

引用

页码：293 / 298

页数：6

共 37 条

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