Crystal structure of 2-tert-butyl-1,3-thiazolo[4,5-b]pyridine

被引:2
作者
El-Hiti, Gamal A. [1 ]
Smith, Keith [2 ]
Hegazy, Amany S. [2 ]
Masmali, Ali M. [1 ]
Kariuki, Benson M. [2 ]
机构
[1] King Saud Univ, Coll Appl Med Sci, Dept Optometry, Cornea Res Chair, POB 10219, Riyadh 11433, Saudi Arabia
[2] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
关键词
crystal structure; C-H center dot center dot center dot N contacts; 1,3-thiazolo[4,5-b]pyri]pyridine;
D O I
10.1107/S160053681401633X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C10H12N2S, does not contain any strong hydrogen-bond donors but two long C-H center dot center dot center dot N contacts are observed in the crystal structure, with the most linear interaction linking molecules along [010]. The ellipsoids of the tert-butyl group indicate large librational motion.
引用
收藏
页码:O932 / +
页数:6
相关论文
共 13 条
[1]  
Agilent, 2014, CRYSALIS PRO
[2]  
Cambridge Soft, 2001, CHEMDRAW ULTR
[3]   SYNTHESIS AND ANTIOXIDANT ACTIVITY EVALUATION OF NOVEL 5,7-DIMETHYL-3H-THIAZOLO[4,5-b]PYRIDINES [J].
Chaban, Taras I. ;
Ogurtsov, Volodymyr V. ;
Chaban, Ihor G. ;
Klenina, Olena V. ;
Komarytsia, Josef D. .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2013, 188 (11) :1611-1620
[4]   A convenient procedure for the formation of 2-substituted thiazolopyridines [J].
El-Hiti, GA .
MONATSHEFTE FUR CHEMIE, 2003, 134 (06) :837-841
[5]   A concise synthesis of 7-chloro-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile, a versatile intermediate for substituted 6-cyanothiazolopyridines [J].
Johnson, Sigmond G. ;
Connolly, Peter J. ;
Murray, William V. .
TETRAHEDRON LETTERS, 2006, 47 (28) :4853-4856
[6]   Solid-Phase Synthesis of Thiazolo[4,5-b]pyridine Derivatives Using Friedlander Reaction [J].
Lee, Taeho ;
Lee, Doohyun ;
Lee, Ill Young ;
Gong, Young-Dae .
JOURNAL OF COMBINATORIAL CHEMISTRY, 2010, 12 (01) :95-99
[7]   Use of intensity quotients and differences in absolute structure refinement [J].
Parsons, Simon ;
Flack, Howard D. ;
Wagner, Trixie .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2013, 69 :249-259
[8]   Synthesis and structure-activity relationships of 2-(1,4′-bipiperidin-1′-yl)thiazolopyridine as H3 receptor antagonists [J].
Rao, Ashwin U. ;
Palani, Anandan ;
Chen, Xiao ;
Huang, Ying ;
Aslanian, Robert G. ;
West, Robert E., Jr. ;
Williams, Shirley M. ;
Wu, Ren-Long ;
Hwa, Joyce ;
Sondey, Christopher ;
Lachowicz, Jean .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2009, 19 (21) :6176-6180
[9]   A Single-Step Preparation of Thiazolo[5,4-b]pyridine- and Thiazolo[5,4-c]pyridine Derivatives from Chloronitropyridines and Thioamides, or Thioureas [J].
Sahasrabudhe, Kiran P. ;
Estiarte, M. Angels ;
Tan, Darlene ;
Zipfel, Sheila ;
Cox, Matthew ;
O'Mahony, Donogh J. R. ;
Edwards, William T. ;
Duncton, Matthew A. J. .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2009, 46 (06) :1125-1131
[10]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122