PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .44. PREPARATION OF MOLYBDENUM AND TUNGSTEN DIAZOALKANE-AMINOCARBENE COMPLEXES CIS,TRANS-[MX(2)(NN=CMEPH)(=C(ME)NHBU(T))(PME(2)PH)(2)] (M=MO, W X=CL, BR) FROM DINITROGEN COMPLEXES CIS-[M(N-2)(PME(2)PH)(4)]

被引：5
|
作者：
HARADA, Y [1 ]
AOSHIMA, T [1 ]
MIZOBE, Y [1 ]
OSHITA, H [1 ]
HIDAI, M [1 ]
机构：
[1] UNIV TOKYO, DEPT SYNTHET CHEM, TOKYO 113, JAPAN
来源：
CHEMISTRY LETTERS | 1994年 / 04期
关键词：
D O I：
10.1246/cl.1994.797
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molybdenum and tungsten diazoalkane-isocyanide complexes cis, trans-[MX(2)(NN=CMePh)(CNBu(t))(PMe(2)Ph)(2)] (M = Mo: X = Cl; M = W: X = Cl, Br), derived from cis-[M(N-2)(2)(PMe(2)Ph)(4)], reacted with AlMe(3) to give diazoalkane-aminocarbene complexes cis,trans-[MX(2)(NN=CMePh){=C(Me)NHBu(t)}(PMe(2)Ph)(2)] (3) after hydrolysis, whose structure has been determined by an X-ray analysis for 3a (M = W, X = Cl).
引用
收藏
页码：797 / 800
页数：4
相关论文
共 50 条
12345