ANISOTROPY OF THE ELECTRICAL CONDUCTIVITY OF VO(2) SINGLE CRYSTALS

被引:79
作者
Bongers, P. F. [1 ]
机构
[1] NV Philips Gloeilampenfabrieken, Philips Res Labs, Eindhoven, Netherlands
关键词
D O I
10.1016/0038-1098(65)90032-3
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electrical resistivity p of single crystals of VO(2) has been measured in directions parallel and perpendicular to the {100) (mon.) = {100} (tetr). direction for 180 < T < 650 degrees K. On both sides of the semiconductor-metal transition temperature rho perpendicular to/rho K approximate to 0. 5 (T(t) = 340 degrees K). This result does not agree with Morin's model of metallic conductivity in a narrow 3d-subband, and indicates clearly that the oxygen 2p-orbitals are involved In the conduction mechanism.
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页码:275 / 277
页数:3
相关论文
共 12 条
[1]   NOTE ON CONDUCTION MECHANISM OF VANADIUM SESQUIXIDE [J].
ACKET, GA ;
VOLGER, J .
PHYSICA, 1962, 28 (03) :277-+
[2]  
ANDERSON G, 1956, ACTA CHEM SCAND, V10, P633
[3]  
BONGERS PF, UNPUB
[4]  
FEINLEIB J, ONR TECHN REP
[5]   DIRECT CATION--CATION INTERACTIONS IN SEVERAL OXIDES [J].
GOODENOUGH, JB .
PHYSICAL REVIEW, 1960, 117 (06) :1442-1451
[6]  
GOODENOUGH JB, 1965, B SOC CHIM FR, P1200
[7]  
GOODENOUGH JB, 1963, MAGNETISM CHEM BOND, P249
[8]  
PAUW LG, 1960, REV SCI INSTRUM, V31, P1189
[9]  
PHYS MFJ, 1959, J PHYS, V3, P34
[10]   NEW GROWING METHOD FOR VO2 SINGLE CRYSTALS [J].
SASAKI, H ;
WATANABE, A .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1964, 19 (09) :1748-+