3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION

被引：70
|
作者：
LEMIERE, G
GAO, M
DEGROOT, A
DOMMISSE, R
LEPOIVRE, J
PIETERS, L
BUSS, V
机构：
[1] UNIV ANTWERP,UIA,DEPT PHARMACEUT SCI,B-2610 ANTWERP,BELGIUM
[2] GERHARD MERCATOR UNIV GESAMTHSCH DUISBURG,D-47048 DUISBURG,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 13期
关键词：
D O I：
10.1039/p19950001775
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound has been synthesised in racemic form by a biomimetic reaction sequence. The two enantiomers were resolved by column chromatography of one of the synthetic intermediates. On the basis of CD results a tentative absolute configuration for the synthetic enantiomers and natural 3',4-di-O-methylcedrusin is proposed.
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页码：1775 / 1779
页数：5
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