HYDROFORMYLATION OF SOME FUNCTIONALIZED OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES WITH PYDIPHOS AND ITS P-OXIDE

被引：66
作者：
BASOLI, C
BOTTEGHI, C
CABRAS, MA
CHELUCCI, G
MARCHETTI, M
机构：
[1] CNR,IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGRO,I-07100 SASSARI,ITALY
[2] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY
[3] UNIV SASSARI,DIPARTIMENTO CHIM,I-07100 SASSARI,ITALY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 488卷 / 1-2期
关键词：
HYDROFORMYLATION; PYRIDYLPHOSPHINES; CATALYSIS; RHODIUM; N-P LIGANDS;
D O I：
10.1016/0022-328X(94)00037-D
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chiral optically active pyridylphosphines pydiphos (10) and its P-oxide (11) were tested as ligands in rhodium(I) complexes to form catalysts for the enantioselective hydroformylation of some functionalized olefins. These hydroformylation reactions provide in most cases good chemo- and regioselectivity, but unsatisfactory enantioselectivity. In the hydroformylation of styrene, vinyl acetate and phenyl vinyl ether, the Rh-(I) complex containing the P-oxide 11 is remarkably more active than the catalyst formed with the pyridylphosphine analogue 10.
引用
收藏
页码：C20 / C22
页数：3
相关论文
共 18 条
[1]   INFLUENCE OF (P-N) BIDENTATE LIGAND ON RHODIUM-CATALYZED HYDROFORMYLATION OF OLEFINS [J].
ABUGNIM, C ;
AMER, I .
JOURNAL OF MOLECULAR CATALYSIS, 1993, 85 (03) :L275-L278
[2]   PHOSPHINE VS PHOSPHINE OXIDE LIGANDS IN HYDROFORMYLATION REACTIONS [J].
ABUGNIM, C ;
AMER, I .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :115-117
[3]   SYNTHESIS AND RESOLUTION OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE - A P-N CHELATING LIGAND FOR ASYMMETRIC CATALYSIS [J].
ALCOCK, NW ;
BROWN, JM ;
HULMES, DI .
TETRAHEDRON-ASYMMETRY, 1993, 4 (04) :743-756
[4]   PLATINUM(II) COMPLEXES OF UNSYMMETRICAL, POTENTIALLY BIDENTATE LIGANDS [J].
ANDERSON, GK ;
KUMAR, R .
INORGANIC CHEMISTRY, 1984, 23 (24) :4064-4068
[5]   COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS [J].
BADER, A ;
LINDNER, E .
COORDINATION CHEMISTRY REVIEWS, 1991, 108 (01) :27-110
[6]   REACTIVE INTERMEDIATES IN ASYMMETRIC CROSS-COUPLING CATALYZED BY PALLADIUM P-N CHELATES [J].
BAKER, KV ;
BROWN, JM ;
COOLEY, NA ;
HUGHES, GD ;
TAYLOR, RJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) :397-406
[7]   ENANTIOSELECTIVE CATALYSIS BY 1-(1-ISOQUINOLINVL)-2-NAPHTHALENEMETHANOL - AN ATROPISOMERICALLY CHIRAL N-O CHELATING LIGAND [J].
BAKER, RW ;
REA, SO ;
SARGENT, MV ;
SCHENKELAARS, EMC ;
SKELTON, BW ;
WHITE, AH .
TETRAHEDRON-ASYMMETRY, 1994, 5 (01) :45-48
[8]   (-)-(4S,5R)-4-(2-PYRIDYL+-5-(DIPHENYLPHOSPHINO)METHYL-2,2-DIMETHYL-1,3-DIOXOLANE A NEW CHIRAL LIGAND FOR ENANTIOSELECTIVE CATALYSIS [J].
CHELUCCI, G ;
CABRAS, MA ;
BOTTEGHI, C ;
MARCHETTI, M .
TETRAHEDRON-ASYMMETRY, 1994, 5 (03) :299-302
[9]   ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION WITH SULFUR-CONTAINING OXAZOLINE LIGANDS [J].
FROST, CG ;
WILLIAMS, JMJ .
TETRAHEDRON-ASYMMETRY, 1993, 4 (08) :1785-1788
[10]   HYDROFORMYLATION OF STYRENE CATALYZED BY RHODIUM COMPLEXES WITH 2-DIPHENYLPHOSPHINOPYRIDINE [J].
GLADIALI, S ;
PINNA, L ;
ARENA, CG ;
ROTONDO, E ;
FARAONE, F .
JOURNAL OF MOLECULAR CATALYSIS, 1991, 66 (02) :183-190
12