ELECTRON-SPIN-RESONANCE STUDY OF POLYMERIC CHARGE-TRANSFER COMPLEXES

被引：3
作者：
PALANIAPPAN, S [1 ]
SATHYANARAYANA, DN [1 ]
机构：
[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,KARNATAKA,INDIA
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1990年 / 28卷 / 03期
关键词：
Activation energy; Charge‐transfer complexes; ESR spectra; Polymer donor;
D O I：
10.1002/mrc.1260280308
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polymeric charge‐transfer complexes with different polymer donors and monomer acceptors were investigated by electron spin resonance spectroscopy. The spin concentrations, g‐values and line widths in the complexes have been determined. The concentration of the paramagnetic charge‐transfer complexes generally increased with increasing strength of the donor‐acceptor tendencies, and exhibited an exponential temperature dependence of spin concentration characteristic of semiconductors. The paramagnetic charge‐transfer complexes were finally transformed into a diamagnetic product; this was confirmed by electronic spectroscopy. Copyright © 1990 John Wiley & Sons, Ltd.
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页码：233 / 238
页数：6
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