TRANSITION-METAL COMPLEXES OF MONOHYDROXAMIC ACIDS

被引：68

作者：

BROWN, DA

MCKEITH, D

GLASS, WK

机构：

[1] Department of Chemistry, University College, Belfield

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)93409-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of monohydroxamic acids and Fe(III), Co(II), Ni(II) and Cu(II) are shown to involve chelation via the oxygen atoms of the donor ligand. Spectral and magnetic properties of the complexes of Fe(III), Co(II), and Ni(II) indicate octahedral coordination with the latter two metal ions forming polymeric species. The monohydroxamic acid complexes show slightly larger 10Dq values than the corresponding aquo and acetylacetonato complexes. Cu(II) forms a square planar complex probably with a dxy ground state. © 1979.

引用

页码：5 / 10

页数：6

共 21 条

[1] HYDROXAMATKOMPLEXE .2. DIE ANWENDUNG DER PH-METHODE [J].