COORDINATION CHEMISTRY OF ADPO

被引：12

作者：

ARDUENGO, AJ

DIAS, HVR

CALABRESE, JC

机构：

[1] Central Research and Development, Delaware 19880-0328, Experimental Station, Wilmington

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 87卷 / 1-4期

关键词：

ADPO; NICKEL(0); PALLADIUM(II); 8-P-3; 10-P-3; 8-P-4;

D O I：

10.1080/10426509408037435

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hypervalent phosphorous compound, 3,7-di-t-butyl-5-aza-2,8-dioxa-1-phosphabicyclo- 3.3.0 octa-2,4,6-triene (ADPO) forms adducts with chromium, tungsten, nickel and palladium metal centers. All four new adducts contain tetrahedral phosphorous atoms as a result of folding the ADPO unit. Tis folding of the planar 10-P-3 ADPO and 8-P-3 ADPO and the strength of the phosphorous-metal interaction. In the case of a homoleptic palladium(II) complex, dimerization of the coordinated ADPO unit was observed.

引用

页码：1 / 10

页数：10

共 28 条

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[2]

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