CROTONALDEHYDE AND METHYLCROTONALDEHYDE HYDROGENATION OVER PT(111) AND PT80FE20(111) SINGLE-CRYSTALS

被引：153

作者：

BECCAT, P ^{[1
]}

BERTOLINI, JC ^{[1
]}

GAUTHIER, Y ^{[1
]}

MASSARDIER, J ^{[1
]}

RUIZ, P ^{[1
]}

机构：

[1] UNIV JOSEPH FOURIER,SPECTROMETRIE PHYS LAB,F-38402 ST MARTIN DHERES,FRANCE

来源：

JOURNAL OF CATALYSIS | 1990年 / 126卷 / 02期

关键词：

D O I：

10.1016/0021-9517(90)90011-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogenation reactions of crotonaldehyde and methylcrotonaldehyde have been carried out on Pt(111) and Pt80Fe20(111) single crystals. The reactions have been performed in the gaseous phase with a large excess of hydrogen. A noticeable enhancement of activity has been observed by alloying the platinum with iron. The additional methyl group present in the methylcrotonaldehyde greatly increases the selectivity toward formation of the unsaturated alcohol, while only a slight increase of such selectivity is induced by alloying. The results have been compared with the previous experimental results on crotonaldehyde hydrogenation on Pt/SiO2 catalysts and cinnamaldehyde hydrogenation on Pt and Pt80Fe20 particles supported on carbon. © 1990.

引用

页码：451 / 456

页数：6

共 10 条

[1] [Anonymous], 1985, HYDROGENATION METHOD
[2] BECCAT P, IN PRESS SURF SCI
[3] DETERMINATION OF MONOLAYER COVERAGE BY AUGER-ELECTRON SPECTROSCOPY - APPLICATION TO CARBON ON PLATINUM
BIBERIAN, JP
SOMORJAI, GA
[J]. APPLIED SURFACE SCIENCE, 1979, 2 (03) : 352 - 358
[4] ACTIVITY AND SELECTIVITY OF PT-FE/C ALLOYS FOR THE LIQUID-PHASE HYDROGENATION OF CINNAMALDEHYDE TO CINNAMYL ALCOHOL
GOUPIL, D
FOUILLOUX, P
MAUREL, R
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1987, 35 (1-2): : 185 - 193
[5] GOUPIL D, 1986, THESIS LYON
[6] HULTGREN R, 1973, SELECTED VALUES THER, P861
[7] MORAWECK B, 1984, J PHYS S, V47
[8] PEARSON WB, 1964, HDB LATTICE SPACINGS, P650
[9] TULEY WF, 1925, J AM CHEM SOC, V45, P3061
[10] METAL SUPPORT EFFECTS ON THE INTRAMOLECULAR SELECTIVITY OF CROTONALDEHYDE HYDROGENATION OVER PLATINUM
VANNICE, MA
SEN, B
[J]. JOURNAL OF CATALYSIS, 1989, 115 (01) : 65 - 78

← 1 →