PHOSPOROUS-CARBON-HALOGEN COMPOUNDS .13. ON THE REACTION OF TRIMETHYLSILYL-SUBSTITUTED METHYLDIPHENYLPHOSPHANES WITH TETRACHLOROMETHANE

被引：10

作者：

APPEL, R

SCHOLER, HF

机构：

[1] Anorganisch-Chemisches Institut Der Universität Bonn, Bonn, D-5300

来源：

CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 03期

关键词：

D O I：

10.1002/cber.19791120329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the Reaction of Trimethylsilyl‐substituted Methyldiphenylphosphanes with Tetrachloromethane In dichloromethane the [(trimethylsilyl)methyl]‐substituted phosphanes 3a, b undergo a chloroform elimination with CCl4 to give the chloromethylenediphenylphosphoranes 4a, b. The new P‐chloro ylides are remarkably stable and can be isolated as pure substances. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1068 / 1070

页数：3

共 6 条

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[4] PHOSPHORUS-CARBON-HALOGEN COMPOUNDS .10. REACTIONS OF TRIPHENYL (TRICHLOROMETHYL) PHOSPHONIUM CHLORIDE WITH TERTIARY PHOSPHANES [J].

APPEL, R ;

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CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (02) :462-467

[5]

APPEL R, UNPUBLISHED

[6]

Cooper B. E., 1970, J ORGANOMET CHEM, V21, P329

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