STUDIES ON THE PROCESS AND PRODUCTS OF MULTIMETHACRYLATE POLYMERIZATION

被引:12
作者
JANTAS, R [1 ]
POLOWINSKI, S [1 ]
STROBIN, G [1 ]
机构
[1] INST CHEM FIBRES,PL-90570 LODZ,POLAND
关键词
MULTIMETHACRYLATE; POLY(2-METHACRYLOYLOXYETHYL METHACRYLATE); TEMPLATE POLYMERIZATION; LADDER POLYMER;
D O I
10.1002/pi.1995.210370410
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Free-radical polymerisation of multimethacrylate-poly(2-methacryloyloxyethyl methacrylate)-in dilute dioxan solutions was examined. The effects of the multimethacrylate molecular weight and the multimonomer concentration on the polymerisation rate and molecular weight distribution and molecular weights of the polymerisation products were determined. The extent of conversion of double bonds in multimethacrylate was determined by FTIR spectrometry, while the molecular weight distributions were determined by gel permeation chromatography. The effect of the parameters under investigation on the template mechanism of the multimethacrylate polymerisation is discussed.
引用
收藏
页码:315 / 318
页数:4
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