EFFECT OF WATER ON TRIBUTYLPHOSPHINE MODIFIED COBALT CARBONYL CATALYSTS FOR THE HYDROFORMYLATION OF OLEFINS

被引：17

作者：

BARTIK, T ^{[1
]}

BARTIK, B ^{[1
]}

HANSON, BE ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 85卷 / 02期

关键词：

CARBONYL COMPLEXES; COBALT; HYDROFORMYLATION; OLEFINS; TRIBUTYLPHOSPHINE; WATER;

D O I：

10.1016/0304-5102(93)80094-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water is seen to have a dramatic effect on the alcohol/aldehyde distribution in the P(nBu)3 modified cobalt carbonyl catalyzed hydroformylation of 1-octene. In particular the rate of alcohol synthesis is greater in the presence of water. Under the conditions used the effect is first noticable at 5 vol.-% water. At high conversion the effect is still observed but is not as significant.

引用

页码：121 / 129

页数：9

共 15 条

[1] ANDREETTA A, 1978, NOUV J CHIM, V2, P463
[2] SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .2. HYDROFORMYLATION OF LINEAR, TERMINAL AND INTERNAL OLEFINS
ARHANCET, JP
DAVIS, ME
HANSON, BE
[J]. JOURNAL OF CATALYSIS, 1991, 129 (01) : 100 - 105
[3] SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .1. NEW METHODS OF PREPARATION
ARHANCET, JP
DAVIS, ME
HANSON, BE
[J]. JOURNAL OF CATALYSIS, 1991, 129 (01) : 94 - 99
[4] WATER-SOLUBLE ELECTRON-DONATING PHOSPHINES - SULFONATION OF TRIS(OMEGA-PHENYLALKYL)PHOSPHINES
BARTIK, T
BARTIK, B
HANSON, BE
GUO, I
TOTH, I
[J]. ORGANOMETALLICS, 1993, 12 (01) : 164 - 170
[5] BARTIK T, UNPUB J ORGANOMET CH
[6] HYDROFORMYLATION OF 1-HEXENE WITH PT(P(M-C6H4SO3NA)3)2CL2 AND ITS TIN CHLORIDE ANALOG ON A CONTROLLED-PORE GLASS
GUO, I
HANSON, BE
TOTH, I
DAVIS, ME
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 70 (03): : 363 - 368
[7] BIS[TRIS(META-(SODIUM SULFONATO)PHENYL)PHOSPHINE] HEXACARBONYL DICOBALT, CO2(CO)6(P(META-C6H4SO3NA)3)2, IN A SUPPORTED AQUEOUS PHASE FOR THE HYDROFORMYLATION OF 1-HEXENE
GUO, I
HANSON, BE
TOTH, I
DAVIS, ME
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) : 221 - 227
[8] KOHL G, 1984, Patent No. 206374
[9] MASON RF, 1968, Patent No. 3400263
[10] Slaugh L. H., 1969, U.S. Patent, Patent No. [3,448,157, 3448157]

← 1 2 →