EFFECT OF WATER ON TRIBUTYLPHOSPHINE MODIFIED COBALT CARBONYL CATALYSTS FOR THE HYDROFORMYLATION OF OLEFINS

被引：17

作者：

BARTIK, T ^{[1
]}

BARTIK, B ^{[1
]}

HANSON, BE ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 85卷 / 02期

关键词：

CARBONYL COMPLEXES; COBALT; HYDROFORMYLATION; OLEFINS; TRIBUTYLPHOSPHINE; WATER;

D O I：

10.1016/0304-5102(93)80094-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water is seen to have a dramatic effect on the alcohol/aldehyde distribution in the P(nBu)3 modified cobalt carbonyl catalyzed hydroformylation of 1-octene. In particular the rate of alcohol synthesis is greater in the presence of water. Under the conditions used the effect is first noticable at 5 vol.-% water. At high conversion the effect is still observed but is not as significant.

引用

页码：121 / 129

页数：9

共 15 条

[1]

ANDREETTA A, 1978, NOUV J CHIM, V2, P463

[2] SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .2. HYDROFORMYLATION OF LINEAR, TERMINAL AND INTERNAL OLEFINS [J].

ARHANCET, JP ;

DAVIS, ME ;

HANSON, BE .

JOURNAL OF CATALYSIS, 1991, 129 (01) :100-105

[3] SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .1. NEW METHODS OF PREPARATION [J].

ARHANCET, JP ;

DAVIS, ME ;

HANSON, BE .

JOURNAL OF CATALYSIS, 1991, 129 (01) :94-99

[4] WATER-SOLUBLE ELECTRON-DONATING PHOSPHINES - SULFONATION OF TRIS(OMEGA-PHENYLALKYL)PHOSPHINES [J].

BARTIK, T ;

BARTIK, B ;

HANSON, BE ;

GUO, I ;

TOTH, I .

ORGANOMETALLICS, 1993, 12 (01) :164-170

[5]

BARTIK T, UNPUB J ORGANOMET CH

[6] HYDROFORMYLATION OF 1-HEXENE WITH PT(P(M-C6H4SO3NA)3)2CL2 AND ITS TIN CHLORIDE ANALOG ON A CONTROLLED-PORE GLASS [J].

GUO, I ;

HANSON, BE ;

TOTH, I ;

DAVIS, ME .

JOURNAL OF MOLECULAR CATALYSIS, 1991, 70 (03) :363-368

[7] BIS[TRIS(META-(SODIUM SULFONATO)PHENYL)PHOSPHINE] HEXACARBONYL DICOBALT, CO2(CO)6(P(META-C6H4SO3NA)3)2, IN A SUPPORTED AQUEOUS PHASE FOR THE HYDROFORMYLATION OF 1-HEXENE [J].

GUO, I ;

HANSON, BE ;

TOTH, I ;

DAVIS, ME .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) :221-227

[8]

KOHL G, 1984, Patent No. 206374

[9]

MASON RF, 1968, Patent No. 3400263

[10]

Slaugh L. H., 1969, U.S. Patent, Patent No. [3,448,157, 3448157]

← 1 2 →