OXYGEN-TRANSFER IN THE REACTIONS OF HYPOFLUOROUS ACID WITH AQUEOUS-SOLUTIONS

被引:18
作者
APPELMAN, EH
THOMPSON, RC
ENGELKEMEIR, AG
机构
[1] Chemistry Division Argonne National Laboratory, Argonne
关键词
D O I
10.1021/ic50194a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Oxygen-18 tracer studies have shown that the reactions of HO*F with H2O and with aqueous HSO4- and Cr(NH3)5N32+ lead to transfer of oxygen with formation of HOO*H, O3SOO*H-, and Cr(NH3)5NO*2+, respectively. Transfer is incomplete in the case of dilute (0.4 M) bisulfate solutions. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码:909 / 911
页数:3
相关论文
共 14 条
[1]  
ANBAR M, 1958, Int J Appl Radiat Isot, V3, P131, DOI 10.1016/0020-708X(58)90007-3
[2]   NONEXISTENT COMPOUNDS - 2 CASE HISTORIES [J].
APPELMAN, EH .
ACCOUNTS OF CHEMICAL RESEARCH, 1973, 6 (04) :113-117
[3]   HYDROXYLATION OF AROMATIC-COMPOUNDS WITH HYPOFLUOROUS ACID [J].
APPELMAN, EH ;
BONNETT, R ;
MATEEN, B .
TETRAHEDRON, 1977, 33 (16) :2119-2122
[4]   REDUCTION OF COORDINATED NITROSYLS .3. ALTERNATIVE ROUTES TO CHROMIUM(III) DIMERS AND EVIDENCE FOR COORDINATED HYDROXYLAMINE [J].
ARMOR, JN ;
BUCHBIND.M ;
CHENEY, R .
INORGANIC CHEMISTRY, 1974, 13 (12) :2990-2996
[5]   THE KINETICS AND MECHANISM OF THE DECOMPOSITION OF CAROS ACID .1. [J].
BALL, DL ;
EDWARDS, JO .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (06) :1125-1129
[6]   PORPHYRIN N-OXIDES [J].
BONNETT, R ;
RIDGE, RJ ;
APPELMAN, EH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (07) :310-311
[7]  
DAVIES R, 1971, INORG CHEM, V10, P1102
[8]   STUDIES ON MECHANISM OF ISOTOPIC OXYGEN EXCHANGE AND REDUCTION OF FERRATE(VI) ION (FEO42-) [J].
GOFF, H ;
MURMANN, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) :6058-&
[9]  
HINDMAN JC, 1972, J CHEM PHYS, V56, P1
[10]   PREPARATION OF CARBON-DIOXIDE FROM SULFATES, SULFUR-DIOXIDE, AIR, AND WATER FOR DETERMINATION OF OXYGEN ISOTOPE RATIO [J].
HOLT, BD .
ANALYTICAL CHEMISTRY, 1977, 49 (12) :1664-1667