PROTON CONDUCTING POLYMER ELECTROLYTE - THE NYLON 6-1O/H3PO4 BLENDS

被引：38

作者：

GRONDIN, J ^{[1
]}

RODRIQUEZ, D ^{[1
]}

LASSEGUES, JC ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,SPECT MOLEC & CRISTALLINE LAB,URA 124,F-33405 TALENCE,FRANCE

来源：

SOLID STATE IONICS | 1995年 / 77卷

关键词：

PROTON CONDUCTOR; POLYMER ELECTROLYTE; NYLON;

D O I：

10.1016/0167-2738(94)00290-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anhydrous Nylon 6-10, xH(3)PO(4) films have been studied by infrared and impedance spectroscopies. The CONH/acid interactions evolve from strong hydrogen bonding to protonation depending on acid concentration and temperature. Protonic conductivity reaches a value as high as 10(-3) S/cm at 25 degrees C for Nylon 6-10, 2.5 H3PO4.

引用

页码：70 / 75

页数：6

共 24 条

[1] THE INFRA-RED SPECTRA AND MOLECULAR CONFIGURATIONS OF POLYAMIDES [J].

CANNON, CG .

SPECTROCHIMICA ACTA, 1960, 16 (03) :302-319

[2]

CHIN DT, 1969, J APPL ELECTROCHEM, V19, P95

[3] INFRARED SPECTROSCOPY OF AMIDE AND CARBOXYLIC ACID INTERACTIONS . HYDROGEN BONDING AND PROTONATION [J].

COMBELAS, P ;

CRUEGE, F ;

LASCOMBE, J ;

QUIVORON, C ;

REYLAFON, M .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1969, 66 (04) :668-&

[4] PROTONATED CARBONYL GROUPS .7. N-ACETYLMORPHOLINE SALTS [J].

COOK, D .

SPECTROCHIMICA ACTA, 1966, 22 (03) :419-&

[5] NMR, CONDUCTIVITY AND NEUTRON-SCATTERING INVESTIGATION OF IONIC DYNAMICS IN THE ANHYDROUS POLYMER PROTONIC CONDUCTOR PEO(H3PO4)X [J].

DONOSO, P ;

GORECKI, W ;

BERTHIER, C ;

DEFENDINI, F ;

POINSIGNON, C ;

ARMAND, MB .

SOLID STATE IONICS, 1988, 28 :969-974

[6] INFRARED STUDIES OF CHAIN FOLDING IN POLYMERS .10. POLYCAPROLACTAM [J].

FRAYER, PD ;

KOENIG, JL ;

LANDO, JB .

JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1972, B 6 (01) :129-&

[7] THE MECHANISM OF ELECTRICAL CONDUCTION IN FUSED PHOSPHORIC AND TRIDEUTEROPHOSPHORIC ACIDS [J].

GREENWOOD, NN ;

THOMPSON, A .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV) :3485-3492

[8]

HAURIE M, 1965, J CHIM PHYS, V62, P137, DOI 10.1051/jcp/1965620137

[9] THE STRUCTURE OF PROTONATED AMIDES AND UREAS AND THEIR THIO ANALOGUES [J].

JANSSEN, MJ .

SPECTROCHIMICA ACTA, 1961, 17 (05) :475-485

[10] SINGLE-CRYSTAL NEUTRON-DIFFRACTION STUDY OF UREA-PHOSPHORIC ACID [J].

KOSTANSEK, EC ;

BUSING, WR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (AUG15) :2454-+

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