SYNTHESIS OF SYN,SYN ANTI,SYN SYN,ANTI AND ANTI,ANTI STEREOTRIADS FROM A SINGLE PAIR OF ENANTIOMERIC REAGENTS

被引：65

作者：

MARSHALL, JA ^{[1
]}

PERKINS, JF ^{[1
]}

WOLF, MA ^{[1
]}

机构：

[1] UNIV S CAROLINA,DEPT CHEM & BIOCHEM,COLUMBIA,SC 29208

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 17期

关键词：

D O I：

10.1021/jo00122a041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stannanes (S)-1a, (R)-1b, and (S)-1c add to (S)- and (R)-2-methyl-3-(benzyloxy)propanal ((S)-2 and (R)-2) to afford the syn,syn (BF3 . OEt(2) promotion), syn,anti (MgBr2 . OEt(2) promotion), anti,anti (SnCl4-derived reagent in CH2Cl2), and anti,syn (SnCl4-derived reagent in hexane) stereotriad adducts 3, 4, 6, and 7.

引用

页码：5556 / 5559

页数：4

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