A NEW APPROACH TO CHIRAL CYCLOPENTADIENYLMETAL COMPLEXES

被引:22
作者
SCHWINK, L [1 ]
VETTEL, S [1 ]
KNOCHEL, P [1 ]
机构
[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY
关键词
D O I
10.1021/om00011a012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new enantioselective synthesis of chiral alpha-oxygen-substituted cyclopentadienyl complexes of Fe and Ru is described. This method does not require a resolution procedure and involves a highly enantioselective preparation of chiral secondary cyclopentadienyl alcohols (89-98% ee).
引用
收藏
页码:5000 / 5001
页数:2
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