catena-Poly[[triaquacopper(II)]-mu-5-carboxybenzene-1,3-dicarboxylato-kappa O-2(1):O-3]

被引：6

作者：

Ma, Yu-Hong ^{[1
]}

Ma, Pi-Zhuang ^{[2
]}

Yao, Ting ^{[1
]}

Hao, Jing-Tuan ^{[1
]}

机构：

[1] Air Force Serv Coll, Xuzhou 2221000, Peoples R China

[2] Logist Coll, Beijing 100858, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813024781

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cu(C9H4O6)(H2O)(3)] n, the Cu II cation exhibits a distorted square-pyramidal coordination geometry involving five O atoms from two monodentate 5-carboxybenzene-1,3-dicarboxylate anions and three water molecules. The 5-carboxybenzene-1,3-dicarboxylate anions bridge Cu-II cations into zigzag polymeric chains running along the b-axis direction. These chains are further linked by O-H center dot center dot center dot O hydrogen bonds between coordinating water molecules or carboxyl groups and carboxylate groups into a three-dimensional supramolecular architecture. In the crystal, pi-pi stacking is observed between parallel benzene rings of adjacent chains, the centroid-centroid distances being 3.584 (3) and 3.684 (3) angstrom.

引用

页码：N538 / +

页数：8

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