ALKYNE INSERTION REACTIONS OF METAL-CARBENES DERIVED FROM ENYNYL ALPHA-DIAZO KETONES [R'CN2COCR2CH2C=C(CH2)N-2CH=CH2]

被引：92

作者：

HOYE, TR

DINSMORE, CJ

JOHNSON, DS

KORKOWSKI, PF

机构：

[1] Department of Chemistry, University of Minnesota, Minneapolis

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 15期

关键词：

D O I：

10.1021/jo00302a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3. © 1990, American Chemical Society. All rights reserved.

引用

页码：4518 / 4520

页数：3

共 27 条

[1] TRANSITION-METAL-CATALYZED REACTIONS OF DIAZO-COMPOUNDS .1. CYCLOPROPANATION OF DOUBLE-BONDS
ANCIAUX, AJ
HUBERT, AJ
NOELS, AF
PETINIOT, N
TEYSSIE, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (04) : 695 - 702
[2] BICYCLO[N.1.0]ALKENES
BILLUPS, WE
HALEY, MM
LEE, GA
[J]. CHEMICAL REVIEWS, 1989, 89 (05) : 1147 - 1159
[3] BINGER P, 1987, TOP CURR CHEM, V135, P77
[4] VINYLCARBENE COMPLEXES OF TITANOCENE
BINGER, P
MULLER, P
BENN, R
MYNOTT, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (05) : 610 - 611
[5] PRACTICAL ORGANIC-SYNTHESIS WITH STRAINED-RING MOLECULES - RHODIUM-CATALYZED CARBONYLATION OF CYCLOPROPENYL ESTERS AND CYCLOPROPENYL KETONES TO ALPHA-PYRONES AND OF VINYL CYCLOPROPENES TO PHENOLS
CHO, SH
LIEBESKIND, LS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (12) : 2631 - 2634
[6] CATALYTIC METHODS FOR METAL CARBENE TRANSFORMATIONS
DOYLE, MP
[J]. CHEMICAL REVIEWS, 1986, 86 (05) : 919 - 939
[7] ELECTROPHILIC METAL CARBENES AS REACTION INTERMEDIATES IN CATALYTIC REACTIONS
DOYLE, MP
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (11) : 348 - 356
[8] REARRANGEMENTS OF OXOCYCLOPROPANECARBOXYLATE ESTERS TO VINYL ETHERS - DISPARATE BEHAVIOR OF TRANSITION-METAL CATALYSTS
DOYLE, MP
VANLEUSEN, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (27) : 5326 - 5339
[9] CORRELATIONS BETWEEN CATALYTIC REACTIONS OF DIAZO-COMPOUNDS AND STOICHIOMETRIC REACTIONS OF TRANSITION-METAL CARBENES WITH ALKENES - MECHANISM OF THE CYCLOPROPANATION REACTION
DOYLE, MP
GRIFFIN, JH
BAGHERI, V
DOROW, RL
[J]. ORGANOMETALLICS, 1984, 3 (01) : 53 - 61
[10] DOYLE MP, 1985, CATALYSIS ORGANIC RE, pCH4

← 1 2 3 →