EFFICIENT UTILIZATION OF VISIBLE-LIGHT IN THE PHOTOREDUCTION OF CHLOROAROMATIC COMPOUNDS

被引：12

作者：

EPLING, GA

WANG, QX

QIU, QW

机构：

[1] Department of Chemistry, University of Connecticut, Storrs

来源：

CHEMOSPHERE | 1991年 / 22卷 / 9-10期

关键词：

D O I：

10.1016/0045-6535(91)90254-B

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Photocatalytic reduction of chloroaromatics to the corresponding aromatic compounds has been accomplished using visible dyes in the presence of amines. An electron transfer mechanism is implicated by the experimental results, with the formation of an aryl chloride radical anion being the key step leading to dechlorination.

引用

页码：959 / 962

页数：4

共 14 条

[1]

ACKERMAN DG, 1983, DESTRUCTION DISPOSAL

[2]

BUNCE NJ, 1982, J ORG CHEM, V47, P1948, DOI 10.1021/jo00349a024

[3] HYDRIDE ENHANCED PHOTOREACTION OF CHLORODIBENZODIOXINS [J].