SYNTHESIS AND COMPLEX-FORMATION OF 6 NEW UNSYMMETRICAL VIC-DIOXIMES

被引：84

作者：

UCAN, HI ^{[1
]}

MIRZAOGLU, R ^{[1
]}

机构：

[1] UNIV SELCUK,FAC SCI ARTS,DEPT CHEM,KONYA,TURKEY

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1990年 / 20卷 / 04期

关键词：

D O I：

10.1080/00945719008048146

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

anti-Chlorophenylglyoxime (CPGH2) has been synthesized by chlorination of anti-phenylglyoxime, The reaction of CPGH2 with suitable aryl- or arylalkylamines in ethanol at -10°C gives the unsymmetrical vic-dioximes, namely, anilinophenylglyoxime (APGH2) p-toluidinophenylglyoxime (PTPGH2), o-toluidinophenylglyoxime (0TPGH2), benzilaminophenylglyoxime (BAPGH2), p-anisidinophenyl-glyoxime (PAPGH2), 1-naphthylaminophenylglyoxime (NAPGH2) The Cu(II) and Ni(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, IR and UV-VIS data are given. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：437 / 449

页数：13

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