INTRA-MOLECULAR MOBILITY OF PENTACOORDINATED TIN-COMPOUNDS

被引：37

作者：

MUGGE, C

JURKSCHAT, K

TZSCHACH, A

ZSCHUNKE, A

机构：

[1] Department of Chemistry, Martin-Luther-University Halle-Wittenberg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)86697-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1H and 13C NMR data for some N-methyl-5,5-dialkyldiptychthiaazstannolidines are reported. The differing coupling constants of the proton signals of the two nonequivalent Sn-alkyl groups suggest apical/equatorial positions for these groups at the pentacoordinated tin atom. The observed intramolecular process is explained by a dissociation-inversion mechanism. © 1979.

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页码：135 / 139

页数：5

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