Frustrated Lewis Pairs

被引：0

作者：

Mukherjee, Sanjoy ^{[1
]}

Thilagar, Pakkirisamy ^{[1
]}

机构：

[1] IISc, IPC, Bangalore, Karnataka, India

来源：

RESONANCE-JOURNAL OF SCIENCE EDUCATION | 2014年 / 19卷 / 11期

关键词：

Lewis acidity/basicity; stearic congestion; catalysis; H-2; activation;

D O I：

10.1007/s12045-014-0120-0

中图分类号：

G40 [教育学];

学科分类号：

040101 ; 120403 ;

摘要：

The fundamental concept of Lewis acid-base interactions have played a substantial role in the progress of chemistry and enriched its understanding, most significantly in the evolution of coordination compounds. In the last 7 years, the chemistry of Lewis Pairs (i.e., acids and bases) has witnessed a different kind of revolution. Molecular frustration, arising from restrictions preventing Lewis acid-base adduct formation has attracted significant attention in metal-free catalysis and activation of small molecules1. In this article, the basic concepts of such frustrated Lewis Pairs are discussed.

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页码：1017 / 1027

页数：11

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