Hydrolysis of Thallium Phthalimide. The Crystal Structure of Dimorph Polymeric Thallium(I) Complex, {Tl[(Hphthalate)]}(n)

被引：0

作者：

Abu-Salem, Qutaiba ^{[1
]}

Mallah, Eyad ^{[2
]}

Said, Farouq F. ^{[1
]}

Ali, Basem F. ^{[1
]}

Steinmann, Manfred ^{[3
]}

Voelter, Wolfgang ^{[4
]}

机构：

[1] Al al Bayt Univ, Fac Sci, Dept Chem, Al Mafraq 25113, Jordan

[2] Petra Univ, Fac Pharm & Med Sci, Amman, Jordan

[3] Univ Tubingen, Inst Inorgan Chem, D-72076 Tubingen, Germany

[4] Univ Tubingen, Interfacultary Inst Biochem, D-72076 Tubingen, Germany

来源：

JORDAN JOURNAL OF CHEMISTRY | 2012年 / 7卷 / 02期

关键词：

Hydrogen Bond; Crystal Structure; Thallium; Phthalate Ligand;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of [Tl(Hphthalate)](n), were grown by hydrolysis of thallium phthalimide during slow evaporation of an aqueous solution at room temperature, and the structure was determined by X-ray diffraction analysis. It has been characterized also by elemental analysis, NMR, and IR spectroscopy. The crystals belong to the monoclinic crystal system space group P2(1)/(c). its crystal structure analysis reveals that there is (TlO6) six coordinate Tl atoms. In addition, the coordination geometry of Tl+ may be influenced by its stereochemically active lone pair. The complex is linked via intermolecular O-H center dot center dot center dot O hydrogen bonding.

引用

页码：163 / 172

页数：10

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