(S)-2,2 '-Dihydroxy-N,N '-(6-hydroxyhexane-1,5-diyl)dibenzamide

被引：0

作者：

Wilbrand, Sabine ^{[1
]}

Neis, Christian ^{[1
]}

Hegetschweiler, Kaspar ^{[1
]}

机构：

[1] Univ Saarland, Fachrichtung Chem, Postfach 151150, D-66041 Saarbrucken, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

data-to-parameter ratio = 8.2; mean σ(C-C) = 0.003 Å; R factor = 0.031; single-crystal X-ray study; T = 123 K; wR factor = 0.076;

D O I：

10.1107/S1600536813000354

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C20H24N2O5, the dihedral angle between the two roughly planar salicylamide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) angstrom] is 25.50 (5)degrees. The molecular conformation is stabilized by intramolecular O-H center dot center dot center dot O hydrogen bonds involving phenol -OH groups and amide O atoms. Intermolecular hydroxymethyl-amide O-H center dot center dot center dot O and amine-hydroxymethyl N-H center dot center dot center dot O hydrogen bonds form infinite chains along the b axis. These chains are further interlinked by amine-amide N-H center dot center dot center dot O and phenol-phenol O-H center dot center dot center dot O interactions, thus giving layers parallel to (001).

引用

页码：O223 / +

页数：9

共 9 条

[1] Brandenburg K., 2012, DIAMOND
[2] Bruker, 2010, APEX2 SAINT SADABS
[3] Synthesis and characterization of a family of binuclear non-heme iron monooxygenase model compounds: Evidence for a "phenolate/amide carbonyl (PAC) shift" upon oxidation
Cappillino, Patrick J.
Tarves, Paul C.
Rowe, Gerard T.
Lewis, Andrew J.
Harvey, Mark
Rogge, Corina
Stassinopoulos, Adonis
Lo, Wayne
Armstrong, William H.
Caradonna, John P.
[J]. INORGANICA CHIMICA ACTA, 2009, 362 (07) : 2136 - 2150
[4] Complexation of molybdenum by siderophores: Synthesis and structure of the double-helical cis-dioxomolybdenum(VI) complex of a bis(catecholamide) siderophore analogue
Duhme, AK
Dauter, Z
Hider, RC
Pohl, S
[J]. INORGANIC CHEMISTRY, 1996, 35 (10) : 3059 - 3061
[5] SYNTHETIC AND STRUCTURAL STUDIES OF A LINEAR BIS-CATECHOL AMIDE, N,N'-BIS(2,3-DIHYDRORRYBENZOYL)-1,7-DIAZAHEPTANE (5-LICAM), AND ITS COMPLEXES WITH NI2+ AND CO2+ - UTILIZATION OF A POLYMER-SUPPORTED, SULFONATED ANALOG, 5-LICAMS, AS A BIOMIMETIC LIGAND FOR DIVALENT METAL-ION REMOVAL FROM AQUEOUS-SOLUTION
HUANG, SP
FRANZ, KJ
OLMSTEAD, MM
FISH, RH
[J]. INORGANIC CHEMISTRY, 1995, 34 (11) : 2820 - 2825
[6] MYXOCHELIN-A, A NEW IRON-CHELATING COMPOUND FROM ANGIOCOCCUS-DISCIFORMIS (MYXOBACTERALES) - PRODUCTION, ISOLATION, PHYSICOCHEMICAL AND BIOLOGICAL PROPERTIES
KUNZE, B
BEDORF, N
KOHL, W
HOFLE, G
REICHENBACH, H
[J]. JOURNAL OF ANTIBIOTICS, 1989, 42 (01) : 14 - 17
[7] Muller P., 2006, CRYSTAL STRUCTURE RE
[8] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[9] Structure and Properties of Copper(II), Manganese(III), and Iron(III) Complexes with Potentially Pentaanionic Heptadentate Ligands Including Alkoxido, Amido, and Phenoxido Donors
Stoicescu, Liliana
Duhayon, Carine
Vendier, Laure
Tesouro-Vallina, Ana
Costes, Jean-Pierre
Tuchagues, Jean-Pierre
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (36) : 5483 - 5493

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