INTRA-MOLECULAR CYCLIZATION OF Z,E,E-1,5,9,-CYCLODODECATRIENE BY THE CP2TICL2-LIALH4 SYSTEM

被引：9

作者：

ANTROPIUSOVA, H ^{[1
]}

MACH, K ^{[1
]}

HANUS, V ^{[1
]}

TURECEK, F ^{[1
]}

SEDMERA, P ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,INST MICROBIOL,CS-14220 PRAGUE 4,CZECHOSLOVAKIA

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 10卷 / 04期

关键词：

D O I：

10.1007/BF02075311

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The system Cp2TiCl2-LiAlH4, in the absence of ethereal solvents, catalyzes the intramolecular cyclization of Z,E,E-1,5,9-cyclododecatriene, yielding a mixture of C12 hydrocarbons consisting mainly of cis, anti, cis-and cis, syn, trans-tricyclo [7.3.0.02,6] dodec-7-ene and 5,6,7,8,9,10-hexahydrobenzocyclooctene. © 1979 Akadémiai Kiadó.

引用

页码：297 / 300

页数：4

共 7 条

[1] PREPARATION OF TITANIUM(III) METALLOCENES BY REDUCTION OF (C5H5)2TICL2 WITH LIALH4.MU-(ETA-5-ETA-5-FULVALENE)-MU-HYDRIDO-MU-CHLORO-BIS-(ETA-5-CYCLOPENTADIENYLTITANIUM)
ANTROPIUSOVA, H
HANUS, V
MACH, K
[J]. TRANSITION METAL CHEMISTRY, 1978, 3 (02) : 121 - 122
[2] HENRICIOLIVE G, 1970, J ORGANOMET CHEM, V21, P377
[3] HYDROMETALATION AND ISOMERIZATION OF OLEFINS BY TITANIUM COMPLEX
ISAGAWA, K
TATSUMI, K
OTSUJI, Y
[J]. CHEMISTRY LETTERS, 1976, (11) : 1145 - 1148
[4] ROLES OF TITANIUM COMPLEX IN CATALYTIC HYDROMETALLATION AND ISOMERIZATION OF OLEFINS
ISAGAWA, K
TATSUMI, K
KOSUGI, H
OTSUJI, Y
[J]. CHEMISTRY LETTERS, 1977, (09) : 1017 - 1020
[5] TURECEK F, TETRAHEDRON
[6] YUREV VP, 1974, DOKL AKAD NAUK SSSR+, V215, P1397
[7] YUREV VP, 1973, ZH OBSHCH KHIM+, V43, P2071

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