HIGH-SPIN 5-COORDINATE COBALT(2) COMPLEXES

被引：50
作者：
DORI, Z
GRAY, HB
机构：
[1] Department of Chemistry, Columbia University
[2] Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena
来源：
INORGANIC CHEMISTRY | 1968年 / 7卷 / 05期
关键词：
D O I：
10.1021/ic50063a010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Preparation and characterization of Co(Et4dien)X2 (Et4dien = HN[CH2CH2N(C2H5)2]2; X = Cl, Br, I, N3, NCS) complexes are reported. Spectral and magnetic properties show that the complexes are high spin and five-coordinate in the solid state. Based on a ligand field model, an interpretation of the observed electronic spectra and magnetic moments is presented. © 1968, American Chemical Society. All rights reserved.
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页码：889 / &
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