STRUCTURAL REINVESTIGATION OF BA3ZR2S7 BY SINGLE-CRYSTAL X-RAY-DIFFRACTION

被引：18

作者：

CHEN, BH ^{[1
]}

EICHHORN, B ^{[1
]}

WONGNG, WN ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,GAITHERSBURG,MD 20899

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193008972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of barium zirconium sulfide, Ba3Zr2S7, were prepared from BaS, Zr and S at 1323 K by using a BaCl2 flux. The compound belongs to the Ruddlesden-Popper (A(n+1) B(n)X3n+1) family with A = Ba, B = Zr, X = S and n = 2. It is isostructural to Sr3Ti2O7 and crystallizes in alternately stacked double perovskite BaZrS3 layers and rocksalt BaS layers.

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页码：161 / 164

页数：4

相关论文

共 11 条

[1] SYNTHESIS AND STRUCTURE OF 2 NEW BA2MS4 PHASES WHERE M = ZR, HF - A NEW SERIES OF K2NIF4 SOLIDS [J].

CHEN, BH ;

EICHHORN, B .

MATERIALS RESEARCH BULLETIN, 1991, 26 (10) :1035-1040

[2] SYNTHESIS AND STRUCTURE OF BA6HF5S16 AND BA5HF4S13 - THE N = 5 AND 4 MEMBERS OF THE AN+1BNX3N+1 RUDDLESDEN-POPPER PHASES [J].

CHEN, BH ;

EICHHORN, BW ;

FANWICK, PE .

INORGANIC CHEMISTRY, 1992, 31 (10) :1788-1791

[3]

CHEN BH, 1993, IN PRESS J SOLID STA

[4] SYNTHESIS AND CRYSTAL STRUCTURES OF SOME ALKALINE EARTH TITANIUM AND ZIRCONIUM SULFIDES [J].

CLEARFIELD, A .

ACTA CRYSTALLOGRAPHICA, 1963, 16 (02) :135-&

[5] STRUCTURE DETERMINATIONS FOR CA3TI2O7, CA4TI3O10, CA3.6SR0.4TI3O10 AND A REFINEMENT OF SR3TI2O7 [J].

ELCOMBE, MM ;

KISI, EH ;

HAWKINS, KD ;

WHITE, TJ ;

GOODMAN, P ;

MATHESON, S .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :305-314

[6]

FAIR CK, 1990, MOLEN INTERACTIVE IN

[7]

Guntert O J, 1956, Z KRISTALLOGR, V107, P357, DOI [10.1524/zkri.1956.107.5-6.357, DOI 10.1524/ZKRI.1956.107.5-6.357]

[8] SULFIDES WITH THE GDFEO3 STRUCTURE [J].

LELIEVELD, R ;

IJDO, DJW .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (OCT) :2223-2226

[9] THE COMPOUND SR3TI2O7 AND ITS STRUCTURE [J].

RUDDLESDEN, SN ;

POPPER, P .

ACTA CRYSTALLOGRAPHICA, 1958, 11 (01) :54-55

[10] NEW COMPOUNDS OF THE K2NIF4 TYPE [J].

RUDDLESDEN, SN ;

POPPER, P .

ACTA CRYSTALLOGRAPHICA, 1957, 10 (08) :538-540