STRUCTURAL REINVESTIGATION OF BA3ZR2S7 BY SINGLE-CRYSTAL X-RAY-DIFFRACTION

被引：17

作者：

CHEN, BH ^{[1
]}

EICHHORN, B ^{[1
]}

WONGNG, WN ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,GAITHERSBURG,MD 20899

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193008972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of barium zirconium sulfide, Ba3Zr2S7, were prepared from BaS, Zr and S at 1323 K by using a BaCl2 flux. The compound belongs to the Ruddlesden-Popper (A(n+1) B(n)X3n+1) family with A = Ba, B = Zr, X = S and n = 2. It is isostructural to Sr3Ti2O7 and crystallizes in alternately stacked double perovskite BaZrS3 layers and rocksalt BaS layers.

引用

页码：161 / 164

页数：4

共 11 条

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