SPECIATION OF SELENIUM AND ARSENIC COMPOUNDS IN NATURAL-WATERS BY CAPILLARY ZONE ELECTROPHORESIS AFTER ON-COLUMN PRECONCENTRATION WITH FIELD-AMPLIFIED INJECTION

被引：72

作者：

LI, K ^{[1
]}

LI, SFY ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE,DEPT CHEM,SINGAPORE 0511,SINGAPORE

来源：

ANALYST | 1995年 / 120卷 / 02期

关键词：

CAPILLARY ZONE ELECTROPHORESIS; ON-COLUMN PRECONCENTRATION; FIELD-AMPLIFIED INJECTION; SELENIUM; ARSENIC;

D O I：

10.1039/an9952000361

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method for the separation and determination of selenium and arsenic compounds by capillary zone electrophoresis (CZE) was developed. On-column enrichment of selenium and arsenic was performed by stacking large volumes of samples injected onto the column with the field-amplified injection technique. Over a 100-fold preconcentration for selenium and arsenic compounds could be achieved within 3.7 min. This method was applied to the determination of selenium and arsenic species in real water samples. The detection limits were below 25 pph. The relative standard deviations for the determination of selenium and arsenic species in water samples were in the range 4.0 to 15.6%.

引用

页码：361 / 366

页数：6

共 38 条

[31] SHAMBERGER RJ, 1986, TRACE ELEM MED, V3, P105
[32] ARSENIC SPECIATION BY ION CHROMATOGRAPHY WITH INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRIC DETECTION
SHEPPARD, BS
CARUSO, JA
HEITKEMPER, DT
WOLNIK, KA
[J]. ANALYST, 1992, 117 (06) : 971 - 975
[33] ANALYTE FOCUSING IN CAPILLARY ELECTROPHORESIS USING ONLINE ISOTACHOPHORESIS
STEGEHUIS, DS
TJADEN, UR
VANDERGREEF, J
[J]. JOURNAL OF CHROMATOGRAPHY, 1992, 591 (1-2): : 341 - 349
[34] DETERMINATION OF ARSENIC(III), ARSENIC(V), ANTIMONY(III), ANTIMONY(V), SELENIUM(IV) AND SELENIUM(VI) BY EXTRACTION WITH AMMONIUM PYRROLIDINEDITHIOCARBAMATE-METHYL ISOBUTYL KETONE AND ELECTROTHERMAL ATOMIC-ABSORPTION SPECTROMETRY
SUBRAMANIAN, KS
MERANGER, JC
[J]. ANALYTICA CHIMICA ACTA, 1981, 124 (01) : 131 - 142
[35] DETERMINATION OF SELENIUM IN SEA-WATER BY ADSORPTIVE CATHODIC STRIPPING VOLTAMMETRY
VAN DEN BERG, CMG
KHAN, SH
[J]. ANALYTICA CHIMICA ACTA, 1990, 231 (02) : 221 - 229
[36] ANALYSIS OF ANION CONSTITUENTS OF URINE BY INORGANIC CAPILLARY ELECTROPHORESIS
WILDMAN, BJ
JACKSON, PE
JONES, WR
ALDEN, PG
[J]. JOURNAL OF CHROMATOGRAPHY, 1991, 546 (1-2): : 459 - 466
[37] CHROMATOGRAPHIC-SEPARATION OF ARSENIC SPECIES WITH SODIUM BIS(TRIFLUOROETHYL)DITHIOCARBAMATE CHELATION
YU, JJ
WAI, CM
[J]. ANALYTICAL CHEMISTRY, 1991, 63 (08) : 842 - 845
[38] STUDY OF ELECTROCHEMICAL REDUCTION OF SELENIUM (+4) USING SQUARE-WAVE VOLTAMMETRY
ZELIC, M
BRANICA, M
[J]. ELECTROANALYSIS, 1990, 2 (06) : 455 - 462

← 1 2 3 4 →