OXIDATIVE CARBONYLATION OF N-BUTYLAMINE USING TRANSITION-METAL CATALYSTS

被引：19

作者：

KANAGASABAPATHY, S ^{[1
]}

GUPTE, SP ^{[1
]}

CHAUDHARI, RV ^{[1
]}

机构：

[1] NATL CHEM LAB, DIV CHEM ENGN, POONA 411008, INDIA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1021/ie00025a001

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Oxidative carbonylation of n-butylamine to methyl N-butylcarbamate has been reported. Several homogeneous and heterogeneous transition metal catalysts have been tested for their activity and selectivity. The effect of promoters, solvents, and temperature has been investigated. Temperature plays a vital role in the selectivity of carbamate.

引用

收藏

页码：1 / 6

页数：6

相关论文

共 29 条

[1] AN EXCEPTIONALLY MILD, CATALYTIC HOMOGENEOUS METHOD FOR THE CONVERSION OF AMINES INTO CARBAMATE ESTERS [J].

ALPER, H ;

HARTSTOCK, FW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (16) :1141-1142

[2] RECENT ADVANCES IN ISOCYANATE CHEMISTRY [J].

ARNOLD, RG ;

NELSON, JA ;

VERBANC, JJ .

CHEMICAL REVIEWS, 1957, 57 (01) :47-76

[3]

BARTON D, 1979, COMPREHENSIVE ORGANI, P1090

[4] HOMOLOGATION OF METHYL ACETATE TO ETHYL-ACETATE WITH RUTHENIUM CATALYSTS .2. EFFECT AND ROLE OF LEWIS AND PROTONIC ACIDS AS PROMOTERS [J].

BRACA, G ;

GALLETTI, AMR ;

SBRANA, G ;

ZANNI, F .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 34 (02) :183-194

[5] CARBONYL HALIDES OF GROUP VIII TRANSITION METALS .5. HALOCARBONYL DERIVATIVES OF RUTHENIUM(III) AND RUTHENIUM(II) [J].

COLTON, R ;

FARTHING, RH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1971, 24 (05) :903-&

[6] LOW-PRESSURE, PALLADIUM-CATALYZED N,N'-DIARYLUREA SYNTHESIS FROM NITRO-COMPOUNDS, AMINES, AND CARBON-MONOXIDE [J].

DIECK, HA ;

LAINE, RM ;

HECK, RF .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (19) :2819-2822

[7] MECHANISTIC INVESTIGATION OF DECACARBONYLDIMANGANESE-CATALYZED CARBONYLATION OF AMINES [J].

DOMBEK, BD ;

ANGELICI, RJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 134 (02) :203-217

[8]

DOMBEK BD, 1992, J CHEM SOC CHEM COMM, P205

[9] FAR INFRARED SPECTRA OF PALLADIUM COMPOUNDS .2. PYRIDINE AND 2,2'-BIPYRIDYL COMPLEXES OF PALLADIUM (2) AND PLATINUM(2) [J].

DURIG, JR ;

MITCHELL, BR ;

SINK, DW ;

WILLIS, JN ;

WILSON, AS .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (04) :1121-&

[10] A NOVEL CATALYTIC SYNTHESIS OF CARBAMATES BY OXIDATIVE ALKOXYCARBONYLATION OF AMINES IN THE PRESENCE OF PALLADIUM AND IODIDE [J].

FUKUOKA, S ;

CHONO, M ;

KOHNO, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (06) :399-400