SYNTHESIS, SPECTRAL AND MAGNETIC INVESTIGATION ON 1-BUTYROYL-4-PHENYL-3-THIOSEMICARBAZIDE COMPLEXES

被引：0
|
作者：
BEKHEIT, MM
机构：
来源：
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE | 1991年 / 05期
关键词：
METAL COMPLEXES; THIOSEMICARBAZIDE; BIDENTATE OR TETRADENTATE LIGAND; SPECTRAL MEASUREMENTS;
D O I：
暂无
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Complexes of 1-butyroyl-4-phenyl-3-thiosemicarbazide (BTSC) with some transition metals have been synthesized and characterized on the basis of elemental analyses, molar conductance, magnetic moment and spectral (visible, IR) studies. The IR spectra show that BTSC behaves as neutral, mononegative and binegative ligand and coordinates in bidentate or bridging tetradentate manner. A tetrahedral structure is proposed for Co(II) complex, square-planer for Ni(II), Pd(II) and Cu(BTSC)Cl2 complexes and octahedral for Cu(BTSC-H)Ac . 2H2O complex according to the data of magnetic and electronic spectral measurements.
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页码：661 / 664
页数：4
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