METAL-AMMONIA SOLUTIONS .3. SPECTROSCOPY OF QUATERNARY AMMONIUM RADICALS

被引：23

作者：

QUINN, RK

LAGOWSKI, JJ

机构：

[1] Department of Chemistry, University of Texas, Austin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 04期

关键词：

D O I：

10.1021/j100850a054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Techniques for the electrolytic generation and the spectroscopic characterization of quaternary ammonium radicals in liquid ammonia have been developed. The spectra of seven tetraalkylammonium radicals in liquid ammonia have been examined in the range 200-2500 mμ. The effects of concentration and temperature, as well as dissolved salts, upon the spectra have been examined. These data indicate that the absorbing species is the same in each case and has the same characteristics as the absorbing species present in metal-ammonia solutions. The implications of these results with respect to the current theories of metal-ammonia solutions are discussed.

引用

页码：1374 / &

共 32 条

[21] ELECTRONIC STRUCTURE OF SODIUM-AMMONIA SOLUTIONS BY NUCLEAR MAGNETIC RESONANCE [J].