MASS-SPECTROMETRIC STUDIES OF SELECTED COUMARINS AND PSORALENS .1. NEGATIVE-IONS

被引:6
|
作者
TKACZYK, M [1 ]
ZOBEL, AM [1 ]
PLOMLEY, JB [1 ]
MARCH, RE [1 ]
机构
[1] INST MACROMOLEC CHEM PETRU PONI, CS-16206 PRAGUE 6, CZECHOSLOVAKIA
来源
ORGANIC MASS SPECTROMETRY | 1993年 / 28卷 / 10期
关键词
D O I
10.1002/oms.1210281028
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An investigation of the negative-ion chemistry of 13 coumarin and three psoralen compounds is reported. Negative-ion chemical ionization was effected using O-. and OH- as the reagent ions; it was found that O-. leads preferably to [M - H + O]- whereas OH- mainly furnishes [M - H]-. The results of metastable anion fragmentation and collision-induced dissociation of mass-selected anions are presented.
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页码:1148 / 1154
页数:7
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