STEREOELECTRONIC REQUIREMENTS FOR A NEW CLASS OF ASYMMETRIC KETONE REDUCTION CATALYSTS CONTAINING AN N-P=O STRUCTURAL UNIT

被引：47

作者：

BURNS, B ^{[1
]}

KING, NP ^{[1
]}

STUDLEY, JR ^{[1
]}

TYE, H ^{[1
]}

WILLS, M ^{[1
]}

机构：

[1] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)86231-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of new catalysts for the asymmetric reductions of ketones by borane are described. The highest accelerations are achieved by catalysts in which the phosphinamide (R(2)NPO) unit can adopt a planar geometry. This observation has provided an insight into the mechanism of catalysis.

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页码：801 / 804

页数：4

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