PHOTOACOUSTIC-SPECTROSCOPY AND RADIANT ENERGY-CONVERSION - THEORY OF THE EFFECT WITH SPECIAL EMPHASIS ON PHOTOSYNTHESIS

被引:163
作者
MALKIN, S [1 ]
CAHEN, D [1 ]
机构
[1] WEIZMANN INST SCI,DEPT CHEM,REHOVOT 76100,ISRAEL
关键词
D O I
10.1111/j.1751-1097.1979.tb07770.x
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Abstract—The use of photoacoustic spectroscopy in the study of photoactive samples (photochemical, luminescent, photovoltaic) is considered. After a short explanation of the parameters important in this technique and ways of measuring them, photochemical processes are considered in detail. Relations are derived for the determination of the energy stored in photochemical products and the quantum yield for the photochemical processes. One‐ and two‐step photochemical processes are treated in detail and the dependence of the photo‐acoustically detected products on modulation frequency is considered, showing the possibility of separating reaction steps according to their rate constants. Particular attention is given to the photosynthetic process and the potential of this method for determination of energy conversion efficiencies of the different stages of photosynthesis is demonstrated. Also the use of the technique in the study of photovoltaic processes is outlined. Copyright © 1979, Wiley Blackwell. All rights reserved
引用
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页码:803 / 813
页数:11
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