1,2,3,4,5-PENTA(4-ALKYLPHEN-1-YL)-1,3-CYCLOPENTADIENES AND THEIR SODIUM, INDIUM(I) AND THALLIUM(I) COMPLEXES

被引：11

作者：

SCHUMANN, H

LENTZ, A

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 12期

关键词：

PENTAPHENYLCYCLOPENTADIENE; (PENTAPHENYLCYCLOPENTADIENYL)SODIUM COMPLEXES; (PENTAPHENYLCYCLOPENTADIENYL)INDIUM(I); COMPLEXES; (PENTAPHENYLCYCLOPENTADIENYL)THALLIUM(I) COMPLEXES;

D O I：

10.1515/znb-1994-1216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Cyclopentadiene pentayl)pentakis[(1,4-phenylene)alkanones] C5H(C6H4C(O)R-4)(5) (R = CH3 (1a), C3H7 (1b), C5H11 (1c), C7H15 (1d)) react with N2H4(H2O)/KOH or Et(3)SiH/CF3COOH to yield the oxygen free ligands C5H(C(6)H(4)CH(2)R-4()5) (2a, 2b, 2c and 2d), which after reaction with NaNH2 give the corresponding sodium salts Na[C-5(C(6)H(4)CH(2)R-4)(5)] (3a, 3b, 3c and 3d). The sodium salts Na[C-5(C6H4C(O)R-4)(5)] (R = CH3 (4a), C5H11 (4c) and 3a react with InCl to give In[C-5(C6H4C(O)R-4)(5)] (5a, 5c) and In[C-5(C(6)H(4)CH(2)R-4)(5)] (6a). 2a, 2b, 2c and 2d react with TlOC2H5 yielding Tl[C-5(C(6)H(4)CH(2)R-4)(5)] (7a, 7b, 7c and 7d). The H-1 and C-13 NMR spectra of the new compounds are reported and discussed.

引用

页码：1717 / 1724

页数：8

共 14 条

[1]

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[2]

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