THE ELECTRONIC ABSORPTION SPECTRA OF DIVALENT COPPER AND NICKEL EDTA COMPLEX CRYSTALS

被引：1

作者：

Zhang Yugeng ^{[1
]}

Li Jianmin ^{[2
]}

机构：

[1] Univ Sci & Technol China, Dept Appl Chem, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Dept Modern Chem, Hefei 230026, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1992年 / 8卷 / 02期

关键词：

Copper and nickel EDTA complex; Electronic absorption spectra;

D O I：

10.3866/PKU.WHXB19920222

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The crystals of complexes [M(H(2)EDTA)H2O] (M=Cu,Ni) are synthesized in aqueous solution. The electronic absorption spectra of these crystals are determined at room temperature. By using of the method of ligand radial wave function scaling theory of 3d orbit, the d-d transition spectra are explained quantitatively, and the d-electron transitions of the electronic absorption spectra are discussed.

引用

页码：251 / 254

页数：4

共 20 条

[1] 5DEGREES CRYSTAL SPECTRA OF NICKEL(II) CHLORIDE AND NICKEL(II) BROMIDE [J].

ACKERMAN, J ;

HOLT, EM ;

HOLT, SL ;

FOUASSIER, C .

INORGANIC CHEMISTRY, 1972, 11 (12) :3118-+

[2] THE DECREASE OF FK-INTEGRALS, TETRAGONAL PERTURBATIONS AND EFFECTS OF AVERAGE ENVIRONMENT IN THE REFLECTION SPECTRA OF NICKEL(II) COMPLEXES [J].

BOSTRUP, O ;

JORGENSEN, CK .

ACTA CHEMICA SCANDINAVICA, 1957, 11 (07) :1223-1231

[3]

Chadakowki A. M., 1964, FARM POLSKA, V20, P37

[4] PREPARATION, SPECTRA AND ELECTRONIC STRUCTURES OF TETRAHEDRAL NICKEL(II) COMPLEXES CONTAINING TRIPHENYLPHOSPHINE AND HALIDE IONS AS LIGANDS [J].

COTTON, FA ;

GOODGAME, DM ;

FAUT, OD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (02) :344-&

[5]

DJINIADHIS G, 1971, CHEM ANAL, V53, P31

[6]

FUJISAWA T, 1989, JPN J APPL PHYS, V28, P1353

[7]

HISHENDS S, 1964, INORG CHEM, V5, P34

[8]

LI JM, 1990, CRYST RES TECHNOL, V25, pK40

[9]

LI JM, 1991, CRYST RES TECHNOL, V26, P331

[10]

LI JM, 1987, CRYST RES TECHNOL, V22, pK154, DOI 10.1002/crat.2170220931

← 1 2 →