The first four moments of the spectral density distribution of an N-electron Hamiltonian matrix defined in an antisymmetric and spin-adapted model space

被引:4
|
作者
Karwowski, J [1 ]
Rajadell, F [1 ]
Planelles, J [1 ]
Mas, V [1 ]
机构
[1] UNIV JAUME 1,DEPT CIENCIAS EXPTL,E-12080 CASTELLO,SPAIN
关键词
D O I
10.1006/adnd.1995.1010
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Expressions for the first four moments of the spectral density distribution of a Hamiltonian matrix describing a system of N spin 1/2 particles are tabulated. The Hamiltonian matrix is defined in a model space of antisymmetrized products of spinorbitals combined to form eigenfunctions of the total spin operators. The moments are given as explicit functions of the interaction integrals and of three integers describing the space (the total number of particles, the total number of orbitals, the total spin quantum number). (C) 1995 Academic Press, Inc.
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页码:177 / 232
页数:56
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