A COFACIAL, DIMERIC, METALLAOXOPHLORIN COMPLEX - [INDIUM(III)(OCTAETHYLOXOPHLORIN)](2)

被引：21

作者：

BALCH, AL

NOLL, BC

OLMSTEAD, MM

REID, SM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001088

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structure of [In(III)(octaethyloxophlorin)]2 shows that the centrosymmetric dimeric structure places the planes of the two macrocycles 3.25 angstrom apart but causes only minimal distortion to the porphyrin-like cores of the molecule.

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页码：1088 / 1090

页数：3

相关论文

共 15 条

[1]

BACH AL, IN PRESS INORG CHEM

[2] STRUCTURAL CHARACTERIZATION OF ZINC(II) COMPLEXES OF OCTAETHYLOXOPHLORIN DIANION AND OCTAETHYLOXOPHLORIN RADICAL-ANION [J].

BALCH, AL ;

NOLL, BC ;

ZOVINKA, EP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (09) :3380-3385

[3]

BISSELL DM, 1986, LIVER NORMAL FUNCTIO, V4, P133

[4]

BLACH AL, 1992, INORG CHEM, V31, P2248

[5] MESO-REACTIVITY OF PORPHYRINS AND RELATED COMPOUNDS .5. MESO-OXIDATION OF METALLOPORPHYRINS [J].

BONNETT, R ;

DIMSDALE, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (20) :2540-&

[6]

CLEZY PS, 1979, PORPHYRINS, V4, P103

[7] CARBON-DIOXIDE INSERTION INTO THE METHYL INDIUM SIGMA-BOND OF METHYLINDIUM(III) PORPHYRINS - MOLECULAR STEREOCHEMISTRY OF (ACETATO) (2,3,7,8,12,13,17,18-OCTAETHYLPORPHYRINATO)INDIUM(III) [J].

COCOLIOS, P ;

GUILARD, R ;

BAYEUL, D ;

LECOMTE, C .

INORGANIC CHEMISTRY, 1985, 24 (13) :2058-2062

[8] THE NATURE OF PI-PI INTERACTIONS [J].

HUNTER, CA ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5525-5534

[9] PYRROLES AND RELATED COMPOUNDS .14. STRUCTURE AND TRANSFORMATIONS OF OXOPHLORINS (OXYPORPHYRINS) [J].

JACKSON, AH ;

KENNER, GW ;

SMITH, KM .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (03) :302-&

[10] THE STRUCTURE OF METHYL(TETRAPHENYLPORPHINATO)INDIUM(III) [J].

LECOMTE, C ;

PROTAS, J ;

COCOLIOS, P ;

GUILARD, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (NOV) :2769-2771