GATEWAY STATES AND BATH STATES IN THE VIBRATIONAL-SPECTRUM OF H-3(+)

被引：0

作者：

LESUEUR, CR ^{[1
]}

HENDERSON, JR ^{[1
]}

TENNYSON, J ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL, DEPT PHYS & ASTRON, LONDON WC1E 6BT, ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 206卷 / 5-6期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibrational band intensities are obtained from discrete variable representation calculations of eigenstates for H-3+. Transitions linking highly excited states to the ground state show large variations in intensities, with gateway states corresponding to highly excited bending motion (''horseshoes'') which leak intensity into the nearby bath states. It is suggested that these gateway states may be observable. Implications of these results for the interpretation of the infrared predissociation spectra of H-3+ are discussed.

引用

页码：429 / 436

页数：8

共 24 条

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