COMMENTS ON - HYDRATE DISSOCIATION ENTHALPY AND GUEST SIZE

被引：45

作者：

SKOVBORG, P

RASMUSSEN, P

机构：

[1] TECH UNIV DENMARK,DEPT CHEM ENGN,DK-2800 LYNGBY,DENMARK

[2] CALSEP AS,DK-2800 LYNGBY,DENMARK

来源：

FLUID PHASE EQUILIBRIA | 1994年 / 96卷

关键词：

THEORY; METHODS OF CALCULATION; DISSOCIATION ENTHALPIES; GAS HYDRATES;

D O I：

10.1016/0378-3812(94)80098-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Sloan and Fleyfel (Sloan, E.D. and Fleyfel, F., 1992. Hydrate dissociation enthalpy and guest size. Fluid Phase Equilibria, 76: 123-140) claim that the dissociation enthalpies of hydrates are determined by the size of the guest molecules, and that they are independent of the type and concentration of the guest gas. This conclusion does not seem to be obvious when the effect of the different amounts of water per mole of gas are eliminated from the data.

引用

页码：223 / 231

页数：9

共 8 条

[1]

[Anonymous], 1984, PERRYS CHEM ENG HDB

[2] THERMODYNAMIC PROPERTIES OF EMPTY LATTICES OF STRUCTURE-I AND STRUCTURE-II CLATHRATE HYDRATES [J].